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Cake day: June 29th, 2023

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  • ornery_chemist@mander.xyztoMemes@sopuli.xyzWhy
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    3 days ago

    For those who did a search only to get back pages of less-than-useless SEO slop that just recites the number line, here is something that better describes some of the grammatical insanity.

    also, czterydzieści cztery is imo one of the less pronounceable words (well, two of them) in Polish.



  • I know that this is partially a joke, but I was trying to figure out what kind of lab would be done to produce chloroform that would be appropriate for students (recent OSHA crackdown on chloromethanes notwithstanding)… haloform reaction I suppose? Is that a common teaching lab experiment?


  • My mom took my little brother to participate in a child psych study like this when he was a toddler (mom had some ties to the university). It was a very similar experiment with skittles as the prize. My brother sat staring glumly at the candy the whole time. The test administrator was increasingly enthusastic with praise after each round right up until the end when she congratulated him and said that he could have the whole bag. He said “no thanks” and ran back to mom crying because he was told there would be candy but they only had skittles, which he very much did not like (and for that matter still doesn’t). The administrator was apparently embarrassed and told my mom that she thought that all kids liked skittles…



  • I realize (and you mentioned) that sugar is not a well defined term, but calling degradation products of ethanol in gas “sugars” is still a bit of a stretch. Ethanol by itself usually forms some combination of acetaldehyde, acetic acid, 2-carbon peroxides, and CO2 (i.e. not sugars) upon autoxidation, though those species can react with other components of gasoline to form the precipitated “gum”. The structure of gum in the literature is pretty hand-wavy (high MW materials kinda just be like that sometimes) but tends to be much more more oxygen-deficient than conventional “sugars” (polysaccharides) even for ethanol blends and contains a wider variety of substructures. Though, I have seen some papers talking about certain microbes that can ferment the ethanol in gasoline, possibly via sugars, but I don’t think that’s the common degradarion pathway for a mower.


  • According to my buddy who worked for Dow, part of these “savings” apparently was taking a hatchet to their R&D segment with a bunch of spray-and-pray layoffs (apparently a common happening these days). I realize Dow is mostly commodity chemicals these days which is much more preservative in nature than other segments of the chemical industry, but even so it sounds like they are killing any hope of competing with new technologies and moving to the “squeeze as much as possible out before it goes tits up” stage.







  • If I stood up straight, my eye level was above the window. Also, glove boxes. The shorter group members could use platforms to raise their height but had trouble reaching the corners, while I had to do a mix of taking an uncomfortably wide stance and slouching. I wish they had been more suitable for my height… I thought everything would be better with taller hoods in my current workplace, but all they did was extend the sash to the floor.


  • I got one because I was intrigued by its lead rotation, but I found that it really didn’t rotate the lead enough while I wrote. I kept having to rotate the barrel manually to keep a thin line like I do for every other mechanical pencil, and then would get annoyed every time the clip came around to brush my hand. I’ve been wondering if I’m doing something wrong, or if Japanese just uses more shorter strokes. Do you also like it when writing English?






  • The intended joke is that hypervalent iodine compounds like Dess-Martin periodinane flip between different oxidation states like you often see for transition metals. As an example, the mechanism usually drawn for oxidations by DMP is similar to those drawn for PCC/Jones reagent, where the electrons removed from the substrate are “banked” at the metal center. Obviously, redox chemistry is not at all limited to transition metals, but I am often surprised at iodine’s propensity to engage in it. A lot of research over the past decade or two has also developed redox catalysis with these reagents, reactivity which is commonly (though again not always) the purview of transition metals.